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Photoflow chemistry setup7/4/2023 ![]() ![]() The current study demonstrates that photoflow synthesis is a viable approach to generate large quantities of monodisperse oligomers. 800 mg of sequence-defined linear chains with 8 repeating units were obtained in a sequential protecting group based 2-step process. A novel photoflow setup designed for a gasliquid biphasic reaction turned out to be useful for the direct use of chlorine gas. Home Photography Darkroom Equipment Chemistry Black & White Film & Paper Chemistry Kodak Photo-Flo. Antoine Duval ab and Luc Avérous a a BioTeam/ICPEES-ECPM, UMR CNRS 7515, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg Cedex 2, France. Video Chat with a Photography Expert - Live. Herein, we present a continuous flow setup employing the light-induced chemistry based on photocaged dienes as a controlled ligation system to establish a new platform for scalable monodisperse macromolecular synthesis. From thermoplastic polyurethane to covalent adaptable network via reversible photo-crosslinking of a biobased chain extender synthesized from caffeic acid. The current study demonstrates that photoflow synthesis is a viable approach to generate large quantities of monodisperse oligomers.ĪB - The development of practical routes that enable the synthesis of unimolecular non-natural macromolecules on multi-gram scales remains a key challenge in polymer chemistry. 800 mg of sequence-defined linear chains with 8 repeating units were obtained in a sequential protecting group based 2-step process. Herein, we present a continuous flow setup employing the light-induced chemistry based on photocaged dienes as a controlled ligation system to establish a new platform for scalable monodisperse macromolecular synthesis. N2 - The development of practical routes that enable the synthesis of unimolecular non-natural macromolecules on multi-gram scales remains a key challenge in polymer chemistry. T1 - Scalable Synthesis of Sequence-Defined Oligomers via Photoflow Chemistry ![]()
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